When I first came across the post of James Bond movies and themes, I emailed it to Jaq. He posted on it, and I commented on his post , so I guess it's time for me to post, now.
Anyway, my comment:
i like the Madonna song, but not best. i also like the 80s songs: The Living Daylights (shades of Take on Me!) and A View to a Kill. also Nobody Does It Better.
of course, it's hard to beat the James Bond Theme itself.
but, the theme aside, my favorite is undoubtedly Live and Let Die.
that man [who sings the newest theme] is Chris Cornell, former lead singer of Soundgarden (eg, Black Hole Sun and Hunger Strike). unsubstantiated hearsay: he studied opera.